Process that results in the interconversion of chemical species.
Energy plays a crucial role in all chemical changes. It is either absorbed or released during these processes. Understanding how energy changes during chemical reactions is fundamental to the study of chemistry.
Physical changes involve a change in the physical properties of a substance, but not its chemical identity. Examples include changes of state, such as melting, freezing, and boiling. In these processes, energy is either absorbed or released, but no new substances are formed.
For instance, when ice melts to form water, it absorbs heat from the surroundings, making this an endothermic process. Conversely, when water freezes to form ice, it releases heat to the surroundings, making this an exothermic process.
Chemical changes, on the other hand, involve a change in the chemical identity of a substance. During a chemical reaction, the reactants are transformed into products, and in this process, energy is either absorbed from or released to the surroundings.
For example, when hydrogen gas reacts with oxygen gas to form water, a significant amount of energy is released in the form of heat and light. This is an exothermic reaction. Conversely, the process of photosynthesis, where plants convert carbon dioxide and water into glucose and oxygen, requires the absorption of light energy, making it an endothermic reaction.
The heat of reaction, also known as the enthalpy change, is the amount of heat absorbed or released during a chemical reaction. It is usually measured using a technique called calorimetry. In an exothermic reaction, the heat of reaction is negative, indicating that heat is released. In an endothermic reaction, the heat of reaction is positive, indicating that heat is absorbed.
Hess's Law states that the total enthalpy change for a chemical reaction is the same, regardless of whether it occurs in one step or several steps. This is because enthalpy is a state function, meaning it only depends on the initial and final states of a system, not the path taken to get there.
Bond energy is the amount of energy required to break a chemical bond. During a chemical reaction, bonds in the reactants are broken and new bonds in the products are formed. If more energy is released in forming the product bonds than is absorbed in breaking the reactant bonds, the reaction is exothermic. Conversely, if more energy is absorbed in breaking the reactant bonds than is released in forming the product bonds, the reaction is endothermic.
Understanding these concepts is crucial for predicting the energy changes that occur in chemical reactions, and for harnessing these energy changes in practical applications, such as the design of energy-efficient chemical processes and the development of new energy sources.